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再硫化胶粉‒SBS复合改性沥青的高低温流变性能试验分析
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1.中交一航局第五工程有限公司,河北 秦皇岛 066000;2.辽宁省交通规划设计院有限责任公司 浙江分公司,浙江 宁波 315100;3.长安大学,陕西 西安 710064

作者简介:

冯浩,男,高级工程师. E-mail:513804097@qq.com

通讯作者:

冯旭冉,男,硕士,助理工程师. E-mail:598786817@qq.com

中图分类号:

U414

基金项目:

中交第一航务工程局有限公司重点研发项目(编号:062024181)


Experimental Analysis of High- and Low-Temperature Rheological Properties of Revulcanized Rubber Powder-SBS Composite Modified Asphalt
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1.No. 5 Engineering Co., Ltd. of CCCC First Harbor Engineering Co., Ltd., Qinhuangdao, Hebei 066000, China;2.Zhejiang Branch, Liaoning Provincial Transportation Planning and Design Institute Co., Ltd., Ningbo, Zhejiang 315100, China;3.Chang’an University, Xi’an, Shaanxi 710064, China

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    摘要:

    为探究脱硫胶粉-SBS复合改性沥青中脱硫胶粉经再硫化处理后的性能恢复效果,该文以18%胶粉-2%SBS复合改性沥青为研究对象,首先通过微波裂解脱硫工艺制备脱硫胶粉-SBS复合改性沥青,在体系中添加硫化剂,成功制备了再硫化胶粉-SBS复合改性沥青。试验确定了胶粉微波脱硫裂解的最佳时间为5 min,硫磺的最佳掺量为脱硫胶粉质量的6%。对比分析了未脱硫、脱硫及再硫化胶粉-SBS 3种复合改性沥青的高、低温流变性能,结果表明:与脱硫胶粉复合改性沥青相比,再硫化胶粉复合改性沥青在高温条件下的黏弹性、变形恢复率及抗变形能力均得到显著提升;同时,其在低温环境中的抗变形能力和耐久性也得到明显改善,且各项性能指标均恢复至未脱硫胶粉-SBS复合改性沥青的水平。红外光谱分析表明,硫化剂的加入能够恢复脱硫胶粉中的C—S键以及部分恢复S—S键。研究结果证实了再硫化处理对脱硫胶粉-SBS复合改性沥青性能恢复的有效性,为相关研究和工程应用提供了理论依据和实践参考。

    Abstract:

    This paper aims to explore the performance recovery of desulfurized rubber powder in the desulfurized rubber powder-SBS composite modified asphalt after revulcanization treatment. By using 18% rubber powder-2% SBS composite modified asphalt, a desulfurized rubber powder-SBS composite modified asphalt was first prepared via a microwave pyrolysis desulfurization process. Subsequently, a vulcanizing agent was added to the system to prepare the revulcanized rubber powder-SBS composite modified asphalt. Experiments determined the optimal microwave pyrolysis desulfurization duration for rubber powder to be 5 min, and the optimal sulfur dosage was 6% by mass of the desulfurized rubber powder. A comparative analysis of the high- and low-temperature rheological properties of three composite modified asphalts (non-desulfurized, desulfurized, and revulcanized) shows that compared to the desulfurized rubber powder composite modified asphalt, the revulcanized rubber powder composite modified asphalt exhibits significantly improved viscoelasticity, deformation recovery rate, and deformation resistance under high-temperature conditions. Meanwhile, its deformation resistance and durability in low-temperature environments are also significantly improved, with all performance indicators restored to the levels of the non-desulfurized rubber powder-SBS composite modified asphalt. Infrared spectroscopy tests indicate that the addition of the vulcanizing agent restores C-S bonds and partially restores S-S bonds in the desulfurized rubber powder. These results confirm the effectiveness of revulcanization treatment in recovering the performance of desulfurized rubber powder-SBS composite modified asphalt, providing a theoretical basis and practical reference for related research and engineering applications.

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引用本文

冯浩,杨照东,冯旭冉,等.再硫化胶粉‒SBS复合改性沥青的高低温流变性能试验分析[J].中外公路,2026,46(1):115-121.
FENG Hao, YANG Zhaodong, FENG Xuran, et al. Experimental Analysis of High- and Low-Temperature Rheological Properties of Revulcanized Rubber Powder-SBS Composite Modified Asphalt[J]. Journal of China & Foreign Highway,2026,46(1):115-121.

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  • 收稿日期:2024-12-30
  • 最后修改日期:2025-05-27
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  • 在线发布日期: 2026-02-05
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